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By D M P Mingos; Robert H Crabtree

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Allred, A. L. J. Inorg. Nucl. Chem. 1961, 17, 215–221. c. Porterfield, W. W. ; Academic Press: New York, 1993, p 46. 18. Jean, Y. In Molecular Orbitals of Transition Metal Complexes; Oxford University Press: New York, 2005, p 13. 19. b a. ; Shlykov, S. ; Volden, H. ; Schno¨ckel, H. Organometallics 1995, 14, 3116–3119. b. ; Roesky, H. W. Curr. Sci. 2000, 78, 410–430. 20. For example, as illustrated by the quote ‘‘Á Á Á assign the complexed ligand the same charge as in its most stable uncoordinated form.

Samuel, E. Inorg. Chem. 1988, 27, 3018–3024. c. ; Kunkely, H. Coord. Chem. Rev. 2004, 248, 273–278. 14a. Collman, J. ; Hegedus, L. ; Norton, J. ; Finke, R. G. In Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, Califorinia, 1987, p 26. b. Crabtree, R. H. In The Organometallic Chemistry of the Transition Metals, 4th edition; Wiley: New York, 2005, p 43. 15a. ; Klapo¨tke, T. ; Hans-Ju¨rgen Meyer, H. ; Reidel, E. Moderne Anorganische Chemie, 2003.

1. As a result of this final transformation, it becomes irrelevant as to whether priority is given to placing the positive charge for cations on either the L- or X-function, although the final classification may be obtained more directly by placing it initially on the L-function. A consideration of some simple compounds serves to indicate the rationale for describing a molecule in terms of its equivalent neutral class. e. [ML3X3] (Figure 29). Thus, even though the compounds have different charges, the CBC method indicates that the three molecules belong to the same class of compound.

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Comprehensive Organometallic Chemistry 3ed Vol 01 by D M P Mingos; Robert H Crabtree

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