Get Halides, Pseudo-Halides and Azides: Volume 1 (1983) PDF

ISBN-10: 0470771712

ISBN-13: 9780470771716

ISBN-10: 0471100870

ISBN-13: 9780471100874

Content:
Chapter 1 Molecular mechanics and conformation (pages 1–47): A. Y. Meyer
Chapter 2 Diamagnetic behaviour of compounds containing carbon–halogen bonds (pages 49–74): R. R. Gupta
Chapter three The mass spectra of azides and halides (pages 75–106): Jack M. Miller and Timothy R. B. Jones
Chapter four Nuclear quadrupole resonance of carbon?bonded halogens (pages 107–159): E. A. C. Lucken
Chapter five 1,2?Dehalogenations and comparable reactions (pages 161–201): Enrico Baciocchi
Chapter 6 Electrochemical oxidation, relief and formation of the C?X bond — direct and oblique strategies (pages 203–286): James Y. Becker
Chapter 7 Pyrolysis of aryl azides (pages 287–320): L. ok. Dyall
Chapter eight Vinyl, aryl and acyl azides (pages 321–368): Harold W. Moore and Dorothy M. Goldish
Chapter nine fresh advances within the radiation chemistry of halocarbons (pages 369–403): Abraham Horowitz
Chapter 10 natural chemistry of astatine (pages 405–440): Klara Berei and Laszlo Vasaros
Chapter eleven optimistic halogen compounds (pages 441–480): A. Foucaud
Chapter 12 facets of the chemistry of halophenols and halodienones (pages 481–548): Judith M. Brittain and Peter B. D. De los angeles Mare
Chapter thirteen ??Halogenated imines (pages 549–601): Norbert De Kimpe and Roland Verhe
Chapter 14 Fluorocarbons (pages 603–655): B. E. Smart
Chapter 15 Xenon halide halogenations (pages 657–679): Marko Zupan
Chapter sixteen The SRN1 response of natural halides (pages 681–701): Robert okay. Norris
Chapter 17 Reactions regarding strong natural halides (pages 703–719): E. Hadjoudis
Chapter 18 Hypervalent halogen compounds (pages 721–811): Gerald F. Koser
Chapter 19 Synthesis and reactivity of ??halogenated ketones (pages 813–931): Roland Verhe and Norbert De Kimpe

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Extra resources for Halides, Pseudo-Halides and Azides: Volume 1 (1983)

Example text

J. Collins and D. N. , 1547 (1970). 132. R. J. Abraham and Z. L. Rossctti, JCS Perkin 2, 582 (1973). 133. K. Tanabe, Specrrochim. Acra, 28A, 407 (1972). 134. L. Fernholt and K. Kvcseth, Acro Chem. , A32, 63 (1 978). 135. F. T. Chau and C. A. McDowell, J. Mol. , 34, 93 (1976). 136. S. Kondo, E. Tagami, K. Iimura and M. Takcda, Bull. Chem. Japan, 41,790 (1968). 137. P. J. D. Park and E. Wyn-Jones, J. Chem. A , 422 (1969). 138. J. G. Kirkwood and F. H. Westheimer,J. Chem. , 6,506, 513 (1938). 139.

T h e first effect (U3, threefold) is some form of bond-bond repulsion. ,twofold) is the stabilizing influence of backdonation from lone-pair orbitals a t one end of the molecule into antibonding a-orbitals at the other, o r of n - c ~ n j u g a t i o n ' ~The ~ . third effect ( U ] ,onefold) is the interaction of dipoles at the two ends of the bond and/or non-bonded i n t e r a c t i ~ n ~ ' ~ . Let us consider the three-term expansions for CH3CHzCHZCH3, ClCHzCHzCl and FCH2CH2F. 5 kcal rno1-I (above Cl/CI-u) for the two barriers, together with data on the conformation CI/CI-g (Table 7).

A. , 5, 205 (1970). J. Trotter in The Chemistry o f t h e Carbon-Halogen Bond (Ed. S . Patai), Part 1, Wiley, London, 1973, p. 49. 5. R. Shaw in The Chemistry of ihe Carbon-Halogen Bond (Ed. S . , 1973, p. 1049. 6. A. Yokozeki and S. H. Bauer, Topics Curr. , 53, 72 (1975). 7. K. H. ), Latidolt-Biirtzstein Zahlenwerte imd Funktionen, New Series, Vol. 11/7, Springer, Berlin, 1976. 8. J. B. Pedley and J. Rylance, Susses N P L Conzputer-ariril)~sed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977.

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