By Lahcene Ouahab
This publication offers a entire assessment on multifunctional molecular fabrics that contain coexistence or interaction or synergy among a number of actual houses targeting electric conductivity, magnetism, single-molecule magnets habit, chirality, spin crossover, and luminescence. The book’s assurance levels from transition metals and lanthanide coordination complexes to real natural fabrics. The ebook additionally discusses a few prospects of purposes of those fabrics in molecule-based units.
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This publication offers a finished evaluation on multifunctional molecular fabrics that contain coexistence or interaction or synergy among a number of actual houses targeting electric conductivity, magnetism, single-molecule magnets habit, chirality, spin crossover, and luminescence. The book’s insurance levels from transition metals and lanthanide coordination complexes to actual natural fabrics.
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Extra info for Multifunctional Molecular Materials
1 D -R 㸩࣭ D -R 㸩࣭ D -R D -R 㸩࣭ D -R D -R (a) Design of spin-polarized donor radical (D–R). Single electron oxidation gives rise to a ground state triplet cation diradical (b) Spin-dependent electron transfer along the alternating arrangement of D–R• and D+•–R•. Conductivity and Magnetism of TTF- and TSF-Based Donor Radicals Molecular Design of a Building Block of Conducting Magnet As a building block for such a ferromagnetic conductor, a series of TTF-based donor radicals (TTF–NN, and others) have been 27 28 Magnetism and Conductivity Ǥ ͳǤͳʹǤͳʹͶȂͳʹ Sugano et al.
Composition of donor and counterion, (ET)ʹCsZn(SCN)4, exhibits similar nonlinear characteristics, obeying the power law of I v V n (n αͺǤͶͲǤʹͻȌǤͳ͵ͻ For the case of (ET)ʹCsZn(SCN)4, the ϐȂ unbinding of electron–hole pairs with a potential barrier of '(E) in the background of the charge-ordered state, where the resistance of the salt is expressed as an Arrhenius type by R = RͲ exp('(E) /kBT) (ͳǤȌ where '(E) ơ Ǥ ơ potential barrier of '(E) decreases with the increasing applied ϐǡ I–V characteristics emerges.
23 Crystal structure of BTBN. (a) Structural formula of BTBN. (b) Molecular arrangement viewed along the c-axis. (c) Columnar stack along the c-axis. 46 Å. The donor planes are overlapped in an inverted manner so as to locate the NN group to the right or left side alternately to avoid steric repulsion. 6 Å between one of the bromine atoms of the dithiole ring and a sulfur atom of the benzodithiole ring in the adjacent stack, while the other bromine atom has close Br… ͵ǤͲ % an oxygen atom of the O–N unit in the NN group of the neighboring molecule.
Multifunctional Molecular Materials by Lahcene Ouahab