Download e-book for iPad: Multifunctional Molecular Materials by Lahcene Ouahab

By Lahcene Ouahab

ISBN-10: 9814364290

ISBN-13: 9789814364294

This publication offers a entire assessment on multifunctional molecular fabrics that contain coexistence or interaction or synergy among a number of actual houses targeting electric conductivity, magnetism, single-molecule magnets habit, chirality, spin crossover, and luminescence. The book’s assurance levels from transition metals and lanthanide coordination complexes to real natural fabrics. The ebook additionally discusses a few prospects of purposes of those fabrics in molecule-based units.

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Multifunctional Molecular Materials by Lahcene Ouahab PDF

This publication offers a finished evaluation on multifunctional molecular fabrics that contain coexistence or interaction or synergy among a number of actual houses targeting electric conductivity, magnetism, single-molecule magnets habit, chirality, spin crossover, and luminescence. The book’s insurance levels from transition metals and lanthanide coordination complexes to actual natural fabrics.

Extra info for Multifunctional Molecular Materials

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1 D -R 㸩࣭ D -R 㸩࣭ D -R D -R 㸩࣭ D -R D -R (a) Design of spin-polarized donor radical (D–R). Single electron oxidation gives rise to a ground state triplet cation diradical (b) Spin-dependent electron transfer along the alternating arrangement of D–R• and D+•–R•. Conductivity and Magnetism of TTF- and TSF-Based Donor Radicals Molecular Design of a Building Block of Conducting Magnet As a building block for such a ferromagnetic conductor, a series of TTF-based donor radicals (TTF–NN, and others) have been 27 28 Magnetism and Conductivity †‡•‹‰‡† ƒ† •›–Š‡•‹œ‡† ƒ• •Š‘™ ‹ ‹‰Ǥ ͳǤͳʹǤͳʹͶȂͳʹ͹ Sugano et al.

Composition of donor and counterion, (ET)ʹCsZn(SCN)4, exhibits similar nonlinear characteristics, obeying the power law of I v V n (n αͺǤͶƒ–ͲǤʹͻȌǤͳ͵ͻ For the case of (ET)ʹCsZn(SCN)4, the ‘Ž‹‡ƒ”…Šƒ”ƒ…–‡”‹•–‹…•ƒ”‡‡š’Žƒ‹‡†„›–Š‡‡Ž‡…–”‹…ϐ‹‡Ž†Ȃ‹†—…‡† unbinding of electron–hole pairs with a potential barrier of '(E) in the background of the charge-ordered state, where the resistance of the salt is expressed as an Arrhenius type by R = RͲ exp('(E) /kBT) (ͳǤ͹Ȍ where '(E) ‹• ƒ ‡ơ‡…–‹˜‡ ’‘–‡–‹ƒŽ „ƒ””‹‡”Ǥ ‹…‡ –Š‡ ‡ơ‡…–‹˜‡ potential barrier of '(E) decreases with the increasing applied ‡Ž‡…–”‹… ϐ‹‡Ž†ǡ ƒ Š‹‰Š ’‘™‡” Žƒ™ ‹ –Š‡ I–V characteristics emerges.

23 Crystal structure of BTBN. (a) Structural formula of BTBN. (b) Molecular arrangement viewed along the c-axis. (c) Columnar stack along the c-axis. 46 Å. The donor planes are overlapped in an inverted manner so as to locate the NN group to the right or left side alternately to avoid steric repulsion. 6 Å between one of the bromine atoms of the dithiole ring and a sulfur atom of the benzodithiole ring in the adjacent stack, while the other bromine atom has close Br… …‘–ƒ…– ‘ˆ ƒ”‘—† ͵ǤͲ % ™‹–Š an oxygen atom of the O–N unit in the NN group of the neighboring molecule.

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Multifunctional Molecular Materials by Lahcene Ouahab


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