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By D. W. Hutchinson, S. Trippett

ISBN-10: 0851860966

ISBN-13: 9780851860961

Organophosphorus Chemistry offers a accomplished annual evaluate of the literature. insurance comprises phosphines and their chalcogenides, phosphonium salts, low coordination quantity phosphorus compounds, penta- and hexa-coordinated compounds, tervalent phosphorus acids, nucleotides and nucleic acids, ylides and comparable compounds, and phosphazenes. The sequence should be of worth to investigate staff in universities, govt and business examine corporations, whose paintings comprises using organophosphorus compounds. It presents a concise yet accomplished survey of an unlimited box of analysis with a wide selection of functions, permitting the reader to speedily continue abreast of the newest advancements of their expert components. professional Periodical stories offer systematic and specified overview insurance of development within the significant components of chemical examine. Written through specialists of their expert fields the sequence creates a different carrier for the energetic learn chemist, delivering commonplace serious in-depth debts of development particularly components of chemistry.

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Chistokletov, L. A. Tamm, and A. A. Petrov,J. Gen. Chem. ), 1977, 47, 696. A. J. Ashe, 111, Accounts Chem. , 1978, 11, 153. l~~ The lone pair at phosphorus is also available for donation to a transition The ‘phosphaphenol’ (199) has been prepared. 201 With the intention of generating P=C bonds by a novel approach, the DielsAlder reaction between the A3-phosphanaphthalene(200) and hexafluorobut-2yne has been studied, in the hope that the adduct (201) would be stable. 202 Cyclization of bisdiphenylphosphinomethane with 1,3-dibromo-2-hydroxypropane gives the cyclic salt (203), which, after conversion into the perchlorate and treatment with phosphoric acid followed by aqueous sodium carbonate, forms the salt (204).

Chem. , 1978, 510. 17 R. R. Holmes and J. A. Deiters, J. Amer. Chem. , 1977, 99, 3318. 18 J. A. Deiters, J. C . Galluci, T. E. Clark, and R. R. Holmes, J. Amer. Chem. ,1977,99, 5461. 3 QuinquecovalentPhosphorus Compounds ro>PN M e, + 35 0' ?? [oq + " MeCO (19) 36 Organophosphorus Chemistry p-electrons on nitrogen in n-bonding. The complex phosphorane (18) is probably formed by rearrangement of the phosphonite (19). R. R. l 9These agree well with experimental values over a wide range of phosphoranes.

Chem. ,1977, 26, 731. D. Rieke, R. A. Copenhafer, C . K. White, A. Aguiar, J. C . , and M. S. Chattha, J. Amer. Chem. ,1977, 99, 6656. B. -R. Dormoy, G. Evin, and C. Selve, J. Chem. Res. ( S ) , 1977, 812; J. Chem. Res. ( M ) , 1977, 2118. B. Evin, C. Selve, and R. Seyer, Synthesis, 1977, 413. S. Lewis, B. J. Walker, and L. M. S. Chem. , 1978,424. H. Kunz, Angew. Chem. Internat. , 1978, 17, 67. 172R. l7* An unexpected reaction of the methylenebisphosphonium salt (171) is its rearrangement to the carbodiphosphorane (172) on deprotonation.

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Organophosphorus Chemistry by D. W. Hutchinson, S. Trippett

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