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Sample text

This represents a fairly typical acidity for water in an NCF C02 extraction process. Since K2 S K3 the hydrogen ion concentration is primarily determined by the initial dissociation of carbonic acid. If the increased acidity is problematic it is possible to suppress the dissociation and buffer the coexisting aqueous phase by addition of 24 D. Steytler bicarbonate anion (Lovell, 1988). The pressure of C 0 2 could, however, be used to control the pH of water in a unique fashion since no chemical residues (of acids or bases) remain.

2. 3764 + 1 . 5 4 2 2 6 ~0- . 2 6 9 9 2 ~ ' )(1 non-sphericity. - T:/*)]' where (w) = the acentric factor representing 32 D. 21) ij a I/, . = (ai U , ) * / ~ (-I k V. 23) ij where kij = an adjustable interaction parameter. One important feature of the van der Waals equation is that it can be expressed in an alternative form that is cubic in volume and, given all other parameters, can be solved analytically for Vi andfi. In the quest to provide improved predictive models for NCF systems the van der Waals equation has provided the starting point for many related cubic equations of state.

To simplify the analysis it will be assumed that the solute to be removed is evenly distributed throughout a particle of regular shape (slab) as shown schematically in Fig. 12. g. sphere, cylinder). _I j. I j. E 0 0 (4 (b) Fig. 12. Schematic representation of the extraction of solute from a slab by (a) the ‘shrinking core’ model and (b) the ‘free diffusion’ model. Mechanism of extraction The solubility of the material to be extracted is clearly a prime factor in determining the effectiveness of a solvent in an extraction process.

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seperation process in food and biotechnology industry


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