By Manabu Kiguchi
This e-book offers a multidisciplinary method of single-molecule electronics. It features a entire review of the sphere, from the synthesis and layout of molecular applicants to the regularly occurring experimental concepts, complemented by way of an in depth theoretical description. This all-inclusive procedure offers the reader with the much-needed viewpoint to totally comprehend the far-reaching ramifications of single-molecule electronics. moreover, a couple of cutting-edge subject matters are mentioned, together with single-molecule spectro-electrical equipment, electrochemical DNA sequencing know-how, and single-molecule chemical reactions. due to this integrative attempt, this booklet can be utilized as an introductory textbook to either graduate and complex undergraduate scholars, in addition to researchers with pursuits in single-molecule electronics, natural electronics, floor technological know-how, and nanoscience.
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Extra info for Single-Molecule Electronics: An Introduction to Synthesis, Measurement and Theory
A distance modulation technique  provides useful information on the formation of the single-molecule junctions and convenient especially when one would like to conduct static measurements such as currentvoltage measurements on a single-molecule junction. In this technique, the distance between two electrodes is modulated at a certain frequency and the AC component of the current synchronizing to the gap distance modulation is measured. In brief, when a current (I) is measured at a gap distance (D D d0 ), the amplitude of the AC current corresponds to dI/dD at d0 that should be close to 0 where the conductance plateau is formed.
Although this deviation can be justified because conductance values for a wide variety of structures are involved in the conductance histogram, it is not straightforward to understand what the peak value and width of the histogram represent. It can represent the most frequently observed plateau and/or the most long-lasting plateau in conductance transient curves. This difference can be problematic especially in low-temperature MCBJ measurements of long molecules because various metastable structures can be stably sustained.
Although the EM method can suffer from several problems, it is still useful to measure electrical gate effects and in the preparation of nanoscale gap electrodes. A novel application of the EM method to create in-plane nano-holes that would open a new application field of the single-molecule measurement techniques is shown. The UHV-LT-STM is capable of forming single-molecule junctions on single-crystal surfaces and manipulating molecules on the surface that enables researchers to study singlemolecule junctions under controlled and well-defined structures and environments.
Single-Molecule Electronics: An Introduction to Synthesis, Measurement and Theory by Manabu Kiguchi