Solid Fuels and Heavy Hydrocarbon Liquids: Thermal - download pdf or read online

By Rafael Kandiyoti

ISBN-10: 0080444865

ISBN-13: 9780080444864

ISBN-10: 0080463959

ISBN-13: 9780080463957

The 1st strand comprises a serious evaluate of the layout of experimental tools used for analyzing the thermal behaviour of stable fuels [pyrolysis, liquefaction and gasification], whereas the second one will emphasise chemical constructions and molecular mass distributions of coal derived tars, extracts and pitches, petroleum-derived asphaltenes, and biomass derived heavy hydrocarbon drinks. significant, interdependent strands within the examine of fossil and renewable gas utilisation are interested in inside of this article: (i) Thermal characterisation of sturdy fuels together with a number of ranks of coals, biomass and waste, and, (ii) The analytical characterisation of heavy hydrocarbon drinks, protecting coal, petroleum and biomass derived heavy fractions. significant, interdependent strands within the research of fossil and renewable gasoline utilisation are curious about inside this article: (i) Thermal characterisation of strong fuels together with numerous ranks of coals, biomass and waste, and, (ii) The analytical characterisation of heavy hydrocarbon drinks, protecting coal, petroleum and biomass derived heavy fractions.

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Additional info for Solid Fuels and Heavy Hydrocarbon Liquids: Thermal Characterisation and Analysis

Sample text

It is now clear, however, that the course of pyrolytic reactions is altered by sample configuration and the presence of the TG-balance pan itself. g. cf. , 1996]. In the case of pyrolysis experiments, however, product distributions are demonstrably affected by the TG-balance configuration. The continued use of these systems to analyse the fundamentals of pyrolytic reactions and, in particular, to evaluate pyrolysis reaction kinetics cannot, in our opinion, be considered a sound procedure. qxd 3/6/06 7:10 PM Page 40 40 Solid Fuels and Heavy Hydrocarbon Liquids: Thermal Characterization and Analysis In this context, it is as well to mention that the level of detail we have just outlined is not always necessary.

1) as well as show a greater proportion of material excluded in size exclusion chromatography (Chapter 8). Statistical structural analysis suggests the presence of linked small (1–4 ring) aromatic clusters in asphaltenes, with a variety of alkyl substituents [Bartle, 1988]. , 1987]. Again, the very high-MM constituents are less-well characterized, since they are insoluble in the more usual NMR solvents. Recent developments in the characterization of the high molecular weight fractions of coal liquids have been based on solubility in 1-methyl-2-pyrrolidinone (NMP) and will be outlined in Chapter 8.

In Yurum Y, (ed) New Trends in Coal Science. p. 1. NATO ASI Series C. Vol. 244. Kluwer, Dordrecht. H. R. (1988). In Yurum Y. (ed) New Trends in Coal Science. p. 53. NATO ASI Series C. Vol. 244. Kluwer, Dordrecht. P. H. (1975). Nature, 261, 77. , Michaelis, W. and Rullkötter, J. (2000) Organic Geochemistry, 31, 945. C. (1995a). E. (ed) Composition, Geochemistry and Conversion of Oil Shales. 125. NATO ASI Series C Vol. 455. Kluwer, Dordrecht. C. (1995b). E. (ed) Composition, Geochemistry and Conversion of Oil Shales.

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Solid Fuels and Heavy Hydrocarbon Liquids: Thermal Characterisation and Analysis by Rafael Kandiyoti


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