By Hong Wei Xiang
The corresponding-states precept is helping the knowledge and calculating of thermodynamic, shipping, and floor houses of gear in a number of states, required by means of our sleek way of life. The Corresponding-States precept and its perform: Thermodynamic, delivery and floor homes of Fluids describes the origins and purposes of the main from a common standpoint with comparisons to experimental information the place attainable. It makes use of the common concept to provide an explanation for current theories. Emphasis is at the homes of natural structures, and the corresponding-states thought is usually prolonged to combinations, that are taken care of as natural platforms. additionally, the writer discusses present development, and exhibits technicians tips to derive functional equations from molecular modeling. The Corresponding-States precept and its perform: Thermodynamic, delivery and floor houses of Fluids is the perfect instruction manual for these in chemical technological know-how and engineering concerning power, atmosphere, ordinary gasoline, and petroleum.* Describes the origins and purposes from a common standpoint* contains experimental info for comparisons* compatible for researchers, utilized engineers, and people attracted to the corresponding states idea
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Extra info for The Corresponding-States Principle and Its Practice: Thermodynamic, Transport and Surface Properties of Fluids
AIChE Annual Meeting (Los Angeles, USA). Xiang, H. , 2001a, Int. J. Thermophys. 22: 919. Xiang, H. , 2001b, J. Phys. Chem. Ref. Data 30: 1161. Xiang, H. , 2001c, Fluid Phase Equilib. 187: 221. Xiang, H. , 2002, Chem. Eng. Sci. 57: 1439. Xiang, H. , 2003, Thermophysicochemical Properties of Fluids: Corresponding -states Principle and Practice (Science Press, Beijing), in Chinese.
Engineers have used this method extensively to obtain estimated properties for design purposes, and many authors have presented charts of both volumetric and related thermodynamic properties on the basis of corresponding states (Pitzer, 1955). 4, the two-parameter corresponding-states principle in terms of the critical parameters is ^ = /(f£). Pc T (4-D c K which is only applicable to monatomic molecules and may cause about 30% error when describing normal fluids. 2 Acentric Factor The difference between spherical molecules and nonspherical molecules was investigated by Pitzer (1955).
Van der Waals, J. , 1873, On the Continuity of the Gaseous and Liquid States, J. S. Rowlinson ed. 14 (North-Holland, Amsterdam). Van der Waals, J. , 1880, Verhand. Kon. Akad. Weten. Amsterdam 20(5): 1; 20(6): 1. Van der Waals, J. , 1881, Ann. Phys. Beibl. 5: 27. Wilding, W. V, J. K. Johnson, and R. L. Rowley, 1987, Int. J. Thermophys. 8: 717. Xiang, H. , 1998, A new simple extended corresponding-states principle for polar fluids: vapor pressure and second virial coefficient, in Proc. 15th IUPAC Int.
The Corresponding-States Principle and Its Practice: Thermodynamic, Transport and Surface Properties of Fluids by Hong Wei Xiang